Hydrogen Sensing of Germany Δ 15th of March 2018 Ω 9:39 AM

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~ Linde Group ~ BASF ~ BMW	~ Daimler ~ Universität Hohenham ~ HyWays	~ Opel ~ Daimler ~ EADS
~ EWE ~ CFC Solutions ~ NUCELLSYS	~ Siemens ~ Hydrogenius ~ IEAHIA	~ Lahmeyer International GmbH ~ sense for Ξ ~ sense for Ξ
~ sense for Ξ ~ sense for Ξ ~ sense for Ξ	~ sense for Ξ ~ sense for Ξ ~ sense for Ξ	~ sense for Ξ ~ sense for Ξ ~ sense for Ξ
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«Hydrogen Sensing	Θ	Θ
ΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞΞ

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~ Linde Group

»Linde Group

»European Hydrogen Association
ξ
»Joachim Wolf

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~ BASF

»BASF
ξ »Horst-Tore

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~ BMW

»BMW
ξ »Klaus Scheuerer

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~ Daimler

»Daimler
ξ »Herbert Kohler

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~ Universität Hohenham

»Universität Hohenham
ξ »Marianne Haug

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~ HyWays

»HyWays

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~ Opel

»Opel

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~ Daimler

»Daimler

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~ EADS

»EADS

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~ EWE

»EWE

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~ CFC Solutions

»CFC Solutions
ξ owner change

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~ NUCELLSYS

»NUCELLSYS

Martin André
ξ NuCellSys GmbH Germany Andre.Martin@NuCellSys.com +49 7021 89 3575
ξ NuCellSys GmbH Germany

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~ Siemens

»Siemens

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~ Hydrogenius

»Hydrogenious

Hydrogenious strategic China partnership with Broad-Ocean Motor
Hydrogenious Technologies entered into a collaboration agreement with Zhongshan Broad-Ocean Motor Co Ltd in China,
as part of the successful third round of financing in the Liquid Organic Hydrogen Carrier (LOHC)
based hydrogen storage specialist.
The partnership to accelerate production of Hydrogenious’ LOHC hydrogen refueling stations, and
establish a large-scale hydrogen mobility infrastructure in China starting in 2019.

Challenges with hydrogen
ξ is in gaseous state at temperatures above -253 °C
ξ has a very low density and is therefore difficult to store
ξ is easily flammable and highly explosive
ξ is a gas with extremely low density
ξ high storage densities are difficult to achieve
ξ at ambient conditions it takes 11 cubic meter to store 1 kilogram of hydrogen
ξ conventional hydrogen storage only works under very high pressures (compressed hydrogen: 700+ bars) or
ξ very low temperatures (liquefied hydrogen: – 253 °C)
ξ this generates additional risks and
ξ requires energy intensive compression and liquefaction procedures

Liquid Organic Hydrogen Carriers (LOHC) as Solution
ξ can be stored and transported under ambient conditions
ξ in the existing fuel infrastructure
ξ without the need for high pressures or low temperatures
ξ one cubic meter of LOHC can store more than 600 cubic meters of hydrogen gas
ξ LOHC is in liquid state from -39°C to 390°C and at ambient pressure
ξ LOHC can store up to 624 Nm3 H2 / Nm3 LOHC
ξ – comparable to storage at 2.000 bar pressure – but in normal steel tanks
ξ LOHC is difficult to inflame, non-explosive and non-toxic

Liquid Organic Hydrogen Carriers (LOHC)
ξ Hydrogenious Technologies developed the breakthrough in hydrogen storage.
ξ The safe and efficient storage of hydrogen in Liquid Organic Hydrogen Carriers (LOHC).
ξ LOHC can be stored and transported under ambient conditions in the existing fuel infrastrucutre
ξ without the need for high pressures or low temperatures.
ξ One cubic meter of LOHC can store more than 600 cubic meters of hydrogen gas and
ξ therefore about 2 MWh of energy.

LOHC technology offers a solution for the so-far unresolved challenge of safe and reliable storage of hydrogen.
Hydrogen is not only a standard gas in industry,
it is often considered to be the energy carrier of the future and
in contrary to the handling of a fugacious and flammable gas,
the storage of hydrogen in liquid LOHC materials is a break-through
on the path towards a clean hydrogen economy.

Due to their Diesel-like nature LOHCs can be transported and distributed
in the existing infrastructure for mineral-oil based fuels.
They are stored in and vice versa released from the LOHC compound
by catalytic hydrogenation and dehydrogenation processes.

Chemical bonding of hydrogen molecules to the liquid carrier via a catalytic reaction @ 50 bar pressure
Exothermal process with 10kWh (th.) / kg H2 usable heat @ 150 °C
Reactor design allows for a continuous hydrogenation process

LOHC Storage Medium
ξ No molecular hydrogen stored
ξ High storage capacity of 6.23 wt.-% equal to 630 Nm3 H2 / m3 LOHC
ξ Storage medium dibenzyltoluene – liquid organic hydrocarbon
ξ Liquid state in a broad temperature range between -39°C to 390°C and ambient pressure
ξ Low flammability and non-explosive – even when loaded with hydrogen
ξ Non-toxic and not classified as dangerous good
ξ Fully reversible loading and unloading of LOHC material possible
ξ No evaporation of stored hydrogen – multi-month storage possible without any losses
ξ Easy storage and transport in commercially available diesel-tanks possible

Dehydrogenation
ξ Release of hydrogen molecules from liquid carrier medium via catalytic reaction
ξ Endothermic process with 10kWh (th.) / kg H2 @ ~300°C required for dehydrogenation
ξ Hydrogen purity ensured via downstream purification
ξ Fully controllable continuous hydrogen release process possible

Hyrdogen utilization
ξ Hydrogen as energy storage medium and re-electrification via fuel cell –
ξ which will be integrated into the LOHC system by Hydrogenious Technologies if required
ξ Hydrogen as a fuel for fuel cell electric vehicles
ξ Hydrogen as a chemical for industrial processes

Hydrogenious’ LOHC technology is based on years of thorough research
in the area of Liquid Organic Hydrogen Carriers (LOHC).
As a spin-off and a company of scientists, engineers and entrepreneurs
Hydrogenious Technologies commercializes LOHC technology and optimizes catalyst and reactor technology.
In addition, Friedrich-Alexander-University Erlangen-Nuremberg (FAU) and
the co-founding professors Wasserscheid, Arlt and Schlücker
continue to push the limits of LOHC technology in their ongoing research efforts.
»lohc-publications-overview

»liquid-organic-hydrogen-carriers by Advanced Science News

Hydrogenious Technologies and broad-ocean motors enter into strategic partnership
Hydrogenious Technologies enters collaboration agreement with Zhongshan Broad-Ocean Motor Co., Ltd. from China.
This relationship is part of the successful third round of financing of the German pioneer in LOHC based hydrogen storage.
The new strategic partnership will accelerate production of Hydrogenious’
LOHC hydrogen refuelling stations and
establish a large scale hydrogen mobility infrastructure in China starting from 2019.

Broad-Ocean Motors is one of the leading companies in the field of hydrogen fuel cells for mobility.
The partnership provides the local production, operation and service for the LOHC systems in China.
China is very serious in transforming the mobility sector to emission-free technologies.
The first LOHC hydrogen refuelling station to be launced in early 2019 and
will use Broad-Ocean’s resources and experience
to ramp up a large-scale roll-out plan over the following years.

The companies will create a network of LOHC hydrogen refuelling stations (HRS) throughout China.
The strategic partnership provides an ideal combination of technology leadership,
market presence and proven execution capability to achieve this goal.

Broad-Ocean is a global manufacturer of electrical components and motors
with an annual production capacity of more than 60 million motors for various purposes,
including the automotive and white goods industries.
»www.broad-ocean.com

Broad-Ocean also operates one of the largest New Energy Vehicle (NEV) fleets in China.
Since 2016, Broad-Ocean has invested in developing technologies for hydrogen mobility in China.
The investment and license agreement with Ballard Power Systems in 2016
marked the starting point for hydrogen-related activities.

At the same time, Anglo American Platinum has increased its investment in Hydrogenious.
Andrew Hinkly, CEO of AP Ventures, Anglo American Platinum’s Corporate Venturing Unit adds,
”Our investment strategy actively supports the development and roll-out of hydrogen related technologies world-wide.
We remain extremely excited about the Hydrogenious’ LOHC technology and
believe this strategic partnership with Broad-Ocean Motors
will accelerate the adoption of Fuel Cell Electric Vehicles in China,
the world’s largest automotive market.”
The UK-based company also is a long-term shareholder in Ballard Power and
supports extensive global network and communication platforms
in the field of hydrogen technology, amongst others the Hydrogen Council.

Hydrogen fueling stations
ξ LOHC significantly simplifies the supply of hydrogen fueling stations
ξ with the large amounts of hydrogen needed by utilizing the existing diesel supply infrastructure
ξ One truck trailer of LOHC contains sufficient hydrogen to fill over 350 cars
ξ A local de-hydrogenation unit allows hydrogen to be released and compressed on demand
ξ The possibility for safe on-site storage of large amounts of hydrogen in LOHC
ξ makes full-scale inner city hydrogen fueling stations possible

LOHC Energy Storage System
ξ No self discharge
ξ Multi-megawatt-hour storage capacity
ξ High safety (no molecular hydrogen stored)
ξ High flexibility (stand alone or LOHC delivery)

ξ Within the storage system hydrogen is produced via electrolysis from renewable electricity.
ξ The hydrogen is then stored in LOHC with a storage density of more than 2 MWh per cubic meter and
ξ without any self discharge.

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~ IEAHIA

»IEAHIA

Jurgen-Friedrich Hake
Institut of Energy Research, Forschungszentrum Jülich GmbH
Head of Programme Group Systems Analysis and Technology Evaluation (IEF-STE)
Leo-Brandt-Str.
D-52428 Jülich, Germany
tel: +49 2461/61-3161
fax: +49 2461/61-2540
e-mail: jfh@fz-juelich.de

Jochen Linssen
Institut of Energy Research, Forschungszentrum Jülich GmbH
Forschungszentrum Jülich GmbH
Leo-Brandt-Str.
D-52428 Jülich, Germany
tel: +49 2461/61-3581
fax: +49 2461/61-2540
e-mail: j.linssen@fz-juelich.de

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~ Lahmeyer International GmbH

»Lahmeyer International GmbH

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